8,165 research outputs found
Membrane-less hybrid flow battery based on low-cost elements
The capital cost of conventional redox flow batteries is relatively high (>USD$ 200/kWh) due to the use of expensive active materials and ion-exchange membranes. This paper presents a membrane-less hybrid organic-inorganic flow battery based on the low-cost elements zinc (92.7% with the use of carbon felt electrodes. In the presence of a fully oxidized active species close to its solubility limit, dissolution of the deposited anode is relatively slow (<2.37 g h−1 cm−2) with an equivalent corrosion current density of <1.9 mA cm−2. In a parallel plate flow configuration, the resulting battery was charge-discharge cycled at 30 mA cm−2 with average coulombic and energy efficiencies of c.a. 71.8 and c.a. 42.0% over 20 cycles, respectively
Cyclohexanedione as the negative electrode reaction for organic redox flow batteries
The electrochemical reduction and oxidation of cyclohexanedione is evaluated for the first time as the negative electrode reaction in an organic redox flow battery. Electrochemical characterization indicates that the redox reaction of cyclohexanedione is a proton-coupled electron transfer process with quasi-reversible behavior in acidic media (pH 2 M) and exhibit reduction process with up to 4 electrons transferred
Out of equilibrium correlation functions of quantum anisotropic XY models: one-particle excitations
We calculate exactly matrix elements between states that are not eigenstates
of the quantum XY model for general anisotropy. Such quantities therefore
describe non equilibrium properties of the system; the Hamiltonian does not
contain any time dependence. These matrix elements are expressed as a sum of
Pfaffians. For single particle excitations on the ground state the Pfaffians in
the sum simplify to determinants.Comment: 11 pages, no figures; revtex. Minor changes in the text; list of
refs. modifie
Draco, a flawless dwarf galaxy
The Draco dwarf spheroidal galaxy (dSph), with its apparent immense mass to
light ratio and compact size, holds many clues to the nature of the enigmatic
dark matter. Here we present deep photometric studies of this dwarf galaxy,
undertaken with the MegaCam Camera at the Canada-France-hawaii Telescope, the
Wide Field Camera at the Isaac Newton Telescope and the Wide-Field and
Planetary Camera on board the Hubble Space Telescope. The new photometric data
cover the entirety of the galaxy, and reach i=24.5 at 50% completeness,
significantly deeper than previous panoramic studies, allowing searches for
tidal disturbances of much lower surface brightness than has been possible
before. With these improved statistics, we find no evidence for asymmetric
disturbances or tidal tails that possess more than 3% of the stars found within
the centre of the galaxy. We find that the central stellar density, as probed
by the HST data, rises into the central 0.5'. Uncertainties in the position of
the centroid of the galaxy do not allow us to determine whether the apparent
flattening of the profile interior to 0.5' is reliable or not. Draco is
therefore a flawless dwarf galaxy, featureless and apparently unaffected by
Galactic tides.Comment: 13 pages, 16 figures, accepted for publication in MNRA
From local monitoring to a broad‐scale viability assessment: a case study for the Bonelli's Eagle in western Europe
Population viability analysis (PVA) has become a basic tool of current conservation practice. However, if not accounted for properly, the uncertainties inherent to PVA predictions can decrease the reliability of this type of analysis. In the present study, we performed a PVA of the whole western European population (France, Portugal, and Spain) of the endangered Bonelli's Eagle (Aquila fasciata), in which we thoroughly explored the consequences of uncertainty in population processes and parameters on PVA predictions. First, we estimated key vital rates (survival, fertility, recruitment, and dispersal rates) using monitoring, ringing, and bibliographic data from the period 1990-2009 from 12 populations found throughout the studied geographic range. Second, we evaluated the uncertainty about model structure (i.e., the assumed processes that govern individual fates and population dynamics) by comparing the observed growth rates of the studied populations with model predictions for the same period. Third, using the model structures suggested in the previous step, we assessed the viability of both the local populations and the overall population. Finally, we analyzed the effects of model and parameter uncertainty on PVA predictions. Our results strongly support the idea that all local populations in western Europe belong to a single, spatially structured population operating as a source-sink system, whereby the populations in the south of the Iberian Peninsula act as sources and, thanks to dispersal, sustain all other local populations, which would otherwise decline. Predictions regarding population dynamics varied considerably, and models assuming more constrained dispersal predicted more pessimistic population trends than models assuming greater dispersal. Model predictions accounting for parameter uncertainty revealed a marked increase in the risk of population declines over the next 50 years. Sensitivity analyses indicated that adult and pre‐adult survival are the chief vital rates regulating these populations, and thus, the conservation efforts aimed at improving these survival rates should be strengthened in order to guarantee the long‐term viability of the European populations of this endangered species. Overall, the study provides a framework for the implementation of multi‐site PVAs and highlights the importance of dispersal processes in shaping the population dynamics of long‐lived birds distributed across heterogeneous landscapes
In the eye of the storm : the Italian economy and the eurozone crisis
The eurozone crisis had a more significant and longer-lasting impact on Italy than on virtually any other member state, with the effects still visible a decade after. The extent of the shock was surprising in view of progress Italy had apparently made in the 1990s in terms of enhancing its capacity to meet the demands of European Monetary Union. The explanation for this traumatic economic experience lies in Italy’s deep, long-term, structural tensions which were placed under severe pressure during the 1990s and which were cracked open by the 2011 sovereign debt crisis. These have had long-standing economic effects as well as political ramifications in terms of a significant change in the Italy–EU relationship
Constraints on the Cosmic-Ray Density Gradient beyond the Solar Circle from Fermi gamma-ray Observations of the Third Galactic Quadrant
We report an analysis of the interstellar -ray emission in the third
Galactic quadrant measured by the {Fermi} Large Area Telescope. The window
encompassing the Galactic plane from longitude 210\arcdeg to 250\arcdeg has
kinematically well-defined segments of the Local and the Perseus arms, suitable
to study the cosmic-ray densities across the outer Galaxy. We measure no large
gradient with Galactocentric distance of the -ray emissivities per
interstellar H atom over the regions sampled in this study. The gradient
depends, however, on the optical depth correction applied to derive the \HI\
column densities. No significant variations are found in the interstellar
spectra in the outer Galaxy, indicating similar shapes of the cosmic-ray
spectrum up to the Perseus arm for particles with GeV to tens of GeV energies.
The emissivity as a function of Galactocentric radius does not show a large
enhancement in the spiral arms with respect to the interarm region. The
measured emissivity gradient is flatter than expectations based on a cosmic-ray
propagation model using the radial distribution of supernova remnants and
uniform diffusion properties. In this context, observations require a larger
halo size and/or a flatter CR source distribution than usually assumed. The
molecular mass calibrating ratio, , is
found to be
in the Local-arm clouds and is not significantly sensitive to the choice of
\HI\ spin temperature. No significant variations are found for clouds in the
interarm region.Comment: Corresponding authors: I. A. Grenier ([email protected]); T.
Mizuno ([email protected]); L. Tibaldo
([email protected]) accepted for publication in Ap
Implications For The Origin Of GRB 051103 From LIGO Observations
We present the results of a LIGO search for gravitational waves (GWs)
associated with GRB 051103, a short-duration hard-spectrum gamma-ray burst
(GRB) whose electromagnetically determined sky position is coincident with the
spiral galaxy M81, which is 3.6 Mpc from Earth. Possible progenitors for
short-hard GRBs include compact object mergers and soft gamma repeater (SGR)
giant flares. A merger progenitor would produce a characteristic GW signal that
should be detectable at the distance of M81, while GW emission from an SGR is
not expected to be detectable at that distance. We found no evidence of a GW
signal associated with GRB 051103. Assuming weakly beamed gamma-ray emission
with a jet semi-angle of 30 deg we exclude a binary neutron star merger in M81
as the progenitor with a confidence of 98%. Neutron star-black hole mergers are
excluded with > 99% confidence. If the event occurred in M81 our findings
support the the hypothesis that GRB 051103 was due to an SGR giant flare,
making it the most distant extragalactic magnetar observed to date.Comment: 8 pages, 3 figures. For a repository of data used in the publication,
go to: https://dcc.ligo.org/cgi-bin/DocDB/ShowDocument?docid=15166 . Also see
the announcement for this paper on ligo.org at:
http://www.ligo.org/science/Publication-GRB051103/index.ph
Sensitivity to Gravitational Waves from Compact Binary Coalescences Achieved during LIGO's Fifth and Virgo's First Science Run
We summarize the sensitivity achieved by the LIGO and Virgo gravitational
wave detectors for compact binary coalescence (CBC) searches during LIGO's
fifth science run and Virgo's first science run. We present noise spectral
density curves for each of the four detectors that operated during these
science runs which are representative of the typical performance achieved by
the detectors for CBC searches. These spectra are intended for release to the
public as a summary of detector performance for CBC searches during these
science runs.Comment: 12 pages, 5 figure
Search for Gravitational Wave Bursts from Six Magnetars
Soft gamma repeaters (SGRs) and anomalous X-ray pulsars (AXPs) are thought to be magnetars: neutron stars powered by extreme magnetic fields. These rare objects are characterized by repeated and sometimes spectacular gamma-ray bursts. The burst mechanism might involve crustal fractures and excitation of non-radial modes which would emit gravitational waves (GWs). We present the results of a search for GW bursts from six galactic magnetars that is sensitive to neutron star f-modes, thought to be the most efficient GW emitting oscillatory modes in compact stars. One of them, SGR 0501+4516, is likely similar to 1 kpc from Earth, an order of magnitude closer than magnetars targeted in previous GW searches. A second, AXP 1E 1547.0-5408, gave a burst with an estimated isotropic energy >10(44) erg which is comparable to the giant flares. We find no evidence of GWs associated with a sample of 1279 electromagnetic triggers from six magnetars occurring between 2006 November and 2009 June, in GW data from the LIGO, Virgo, and GEO600 detectors. Our lowest model-dependent GW emission energy upper limits for band-and time-limited white noise bursts in the detector sensitive band, and for f-mode ringdowns (at 1090 Hz), are 3.0 x 10(44)d(1)(2) erg and 1.4 x 10(47)d(1)(2) erg, respectively, where d(1) = d(0501)/1 kpc and d(0501) is the distance to SGR 0501+4516. These limits on GW emission from f-modes are an order of magnitude lower than any previous, and approach the range of electromagnetic energies seen in SGR giant flares for the first time.United States National Science FoundationScience and Technology Facilities Council of the United KingdomMax-Planck-SocietyState of Niedersachsen/GermanyItalian Istituto Nazionale di Fisica NucleareFrench Centre National de la Recherche ScientifiqueAustralian Research CouncilCouncil of Scientific and Industrial Research of IndiaIstituto Nazionale di Fisica Nucleare of ItalySpanish Ministerio de Educacion y CienciaConselleria d'Economia Hisenda i Innovacio of the Govern de les Illes BalearsFoundation for Fundamental Research on Matter supported by the Netherlands Organisation for Scientific ResearchPolish Ministry of Science and Higher EducationFoundation for Polish ScienceRoyal SocietyScottish Funding CouncilScottish Universities Physics AllianceNational Aeronautics and Space Administration NNH07ZDA001-GLASTCarnegie TrustLeverhulme TrustDavid and Lucile Packard FoundationResearch CorporationAlfred P. Sloan FoundationRussian Space AgencyRFBR 09-02-00166aIPN JPL Y503559 (Odyssey), NASA NNG06GH00G, NASA NNX07AM42G, NASA NNX08AC89G (INTEGRAL), NASA NNG06GI896, NASA NNX07AJ65G, NASA NNX08AN23G (Swift), NASA NNX07AR71G (MESSENGER), NASA NNX06AI36G, NASA NNX08AB84G, NASA NNX08AZ85G (Suzaku), NASA NNX09AU03G (Fermi)Astronom
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